AFor music lists with scene descriptions, go here. You can also find the soundtracks in each episode on The Vampire Diaries Wikia.Chris Mollere, the music supervisor tweets a complete song list after each episode airs in the West Coast (It currently airs Thursdays @8PM ET). Follow him on twitter.
AYes, seasons 1-5 are available to own on DVD, Blu-ray and digital download. Season 6 is currently airing.The Complete First Season was released in both DVD & Blu-ray formats on August 31st, 2010.The Complete Second Season was released in both DVD & Blu-ray formats on August 30th, 2011.The Complete Third Season was released in both DVD & Blu-ray formats on September 11th, 2012.The Complete Fourth Season was released in both DVD & Blu-ray formats on September 3rd, 2013.The Complete Fifth Season was released in both DVD & Blu-ray formats on September 9th, 2014.Seasons 1-5 can be digitally downloaded from iTunes and Amazon. Season 6 episodes will be available after they air.